setValueして、saveで保存する。
let appDelegate = UIApplication.shared.delegate as! AppDelegate
let context = appDelegate.persistentContainer.viewContext
let entity = NSEntityDescription.entity(forEntityName: "Users", in: context)
let newUser = NSManagedObject(entity: entity!, insertInto: context)
newUser.setValue("Louis Miguel", forKey: "username")
newUser.setValue("asdf", forKey: "password")
newUser.setValue("1", forKey: "age")
do {
try context.save()
} catch {
print("Failed saving")
}